HomeMy WebLinkAboutFire Department Recordsnnn,Ivroru,wourvr
Date:March 30, 1995
To:
From:Ronald G. Hanson
File
Subjecfi 21 Santa Rosa, Limit on Quantities of Liquified Helium
On March 22 and23, 1995I telephoned the CSFM's office and OSHPD and requested information with
regard to MRI units and how to handle the quantities of helium in the unit and recharging of the units.
Pat Sanchez, DSFM sent me a memo regarding the use of UFC, Article 75, indicating the CSFM had
not adopted Article 75 (City of SLO, fire department has adopted this article). I also contacted OSHPD
and talked to John Donnaly who used to be a DSFM and fire marshal. John indicated that the quantities
in table 9-A were only for flammable and oxidizing agents. Helium isn't either of these, its a non-
flammable liquified gas. However it is restricted to 1000 lbs. or approx. 100 gallons. The quantity
of helium within the MRI unit is within a sealed system and therefore he would doesn't count this
quantity. The size of portable container that they recharge the MRI unit is only 66 gallons and therefore
there isn't any problems.
FRgr'r 51'r I TH & C0frPnNV 03.22. 1995 t42 t2 P. I
i1
TH and
IUEMo 5$S Ramona Drivo
San Luis Oblspo, CA 03{05
(aos) sac-rscg
5{4-I l?? I|AX
To
Frsm
Date
Subjoct
K-^r llo^rot
(u, rJ;*L
4e{qs
Ir4 tcn
4,t S",t^ &J'.
FILf 88Py
rurg FAx coNTArNs 1 pAcD($ TNcLUDTNG Trrls covrn rAGD
IF T'IIERE HAS I'DIIN A TITANSMISSION PITODI,T}M OII II' I'AGIiS ARII
MIssINc, pIrIlAsD CALL (805) i{i-?3ig
Eoue-,to.oo Arra tl* t4sp= dlqg ItL He.
O*,7lrlz.l .
fro h4n Fa^^ vi 1A4FJ w,tt- a^ elrc'tl ^a vu{ +'^
S Stt fvllcttoruri,aU Off*ni*roJ, t ," lr af"I,ffi A,.nolAnncauu"[
lir*tt {^' 6,8- E1,rrgwfo,f e^-t rd,,l,rrl.r r OMt*k'T,
Lo[ *t k.- 4 rett, n"nl
€o{
*0*\ "t"
Coeloo to
FORM I?
FAX il
FROII 5I'1 I TH g COHPNNV 03.22. 1995 l4: t2 P. 2
rf Fltodrot3 tnd Chmlgdr,
'!olt rliltnoilcgbtll{
Ulehrwn, tf lfiee.lg0t
illphcnr (fi'l.rl-lrtl
lns.
landllng snd 8torego
(r) Never drop cylinderB or pcrmlt
them to strikt cich othor
violontly.
i2) Cyllndero thould be acslgned a
dellnlte aree lor etoregt. The
aroa ehould be dry, cool, wgll
ventllalcd, snd prCtirebfy tlfo
reclrlmt. Keop cylindcrs pr$
tsgtod lrom gxqweiYi tompera.
turoc by Gtodng thcn twry
from ndhtors or olhu gourcgo
ol hcrt,
3) 9llndcru flay bc rtond ln thr
opcn, but ln euch clcct should
bt prolectgd agrinol rxtrsmgS
ol weether and lrom dsmp
ground tg pGvtnt rultlng.
4, The valve protecllon crp
rhould bo lsfl ln plaor untll the
cyltndor hsg bgen socurcd
agrinct l well, a bonch, or
plaocd in r cyllnder ttand, tnd
ls roady lo be ueed.
$) Avolcl Oragging or rlldlng cylln.
dor0. olon tor chort dletancor,
Cyllndere rhould be mowcl by
s eultablt hand truck.
6) De nol uso cylindors ae rollgre
lor mwlng mitarid or othor
oqulpment.
7) Newr tampor wlth orliry do.
vicco ln valves gr cyllndert.
B) When rclurnlng smpty cylln.
ders, crose thr vrlvs bgforc
ehlpment. Lrwl roms poolthc
Pr9t9uf0 h thc cyllrdor. Ro-
plaoe any vatvl outlet end pre
tectlw cApD 0rlgintlly shlpped
wlth tho cyllnder. ilfrk end lr.
bel the cyllnder EMPTY. Do not
ctore lull end empty cyltnder$
logethor,
(0) No prrt ol a cylinder ehoutd be
rubjrcled ta I tcmpor0lure
lbow la6'F (52.C), prwsnl
tprrko or llEmct lrom wotdtng
or cultlng torchr or any olhCr
tourgg lrom comlng ln contact
wlth oyllndrrg. Do nol pcrmtt
cyllndere to corno ln oontrct
wlth elsctriorl lpprntuc or
clrcultr.
(10) Utc rcauletw md pr*suro
ttli?l dfilcss whsn connecilng
cylindrro lo clrqullE havlng
lowcr pruceup jsrvlc! ritlngs.
(ll) Know md understend tho
prgprty. uool, and satity pre
oautions lor hellum bcbre uo.
ing tha ges end/or rseoclrted
!quipment.
(12) Alwryg opcn i hellum cyilndrr
ralvc rlowly.
(13) lf I cyllnder protcctlvs cap le
extremoly dltflcult to romo\ro,
do not rpply oxcoreive lorce or
pry the crp looro lvith i btr ln-
rrlrd lnto ths wnlilition
oponlngr. Allech r tabclor tag
to tho cyllnder ldentifying the
problrm *d ruturn lhr cyllnder
lo thr suppllor,
(14) Wranchrs rhould ngt be uegd
on valvlg oqulppod wllh a
hsndwhegl. lf thc valve tg
fEulty, allach r lebclor leg to
th€ ayllnds ldontltylng the
floblom and rotum the cyllnder
lo thc euppllor.
(t5) Comg0ared gae eyhdfiB
thoufd nol bs relllled oxcrpt by
qurtlfird producsre of som.
Prllltd geses.
(10) Shlpmont of a compreesed gm
cyllnder lliloc wtthout ths soh.
tent ol the owntr ll a vlolatlongtF dtnlLsw.
Pcnonnd Equlpmcnt
$rhly rhopr and gleeess ari Eug.
gcctod whcn worklng wlth cylin(,fis
conlihlng hlgh.prco$re gaees. Pro.
vidc en ak llnc or relf.cqnlalmd
brcethlng ?quipmoil tor parsonnol
who mry bc rrqulrrd lg rvork in Oxy.
gcn.deflolent rlmorpheror. Nrvrr
0ntc? gxygg1.dofi cbnt ltrnotphorol
wlthout eell.conlllncd brorthlng
equlprYuat-awn ln o{ncrgt'roy
sltuatlont.
Fir't Ald
FcrconB oxporcd to oxyeen.doflctent
ilmorpheroe may bocomc cpmtlo
(blut), lnc$sqltated, comitogo. and
brcrthing mty be lmprfrod. Prgmpt
?gsuroitrtion lc uecntlrl. $upply
lrsch alr hm.dirldy, ll breathlng
har rtoppcd or ic lrbored or lnsllec-
tlvo-rsdlled ro*lritlon (s,9.
mouth.to.mouth) L .tccntlal. Ghro
oxygen ll rwllablo. Scck medlcal
rgrlrunco.
Fhc Flghilno
Sincr hillum b nonlltmmrblc,lpa.
Elgl fiil liohtlno oqulpment or ln.
rtruotionc r. not needed.
aall
FROI'I 5H I TH & CO14PRNV
1,
g3 .22. t995 14: l3
')
P. 5
tubes as prrl 0f I stBtlontry tnttrllr.
tlon. Thecs tubrs ere hydrorlaticrlly
tested by thg menufactur9' bul, un.
llko cyllnderr snd moblle tubes, pcri.
odicel hydroslailc tteting la nol
requirtd.
(S) Month andycarof eubscquent
5-yeor or lo.year hydrosl0tlc r0
icsl ol lhe conhlner.
(0) Tho orlolnal tnsptctor'r ldentila.
catlon 3116'P.
Thc neckdng urually ls lctentiltcd by
thc owner's symbol or namo.
$hipment ol Hollum Cyllndrrr
Thg rhlpmrnt ot hollurn cylindors by
gurlacg traneporlatlon mutl conlorm
to Dopartmont of Trsngpoftttlon
Fegulatlone aE sct lotth ln lhO Code
ol F?deral Regutationg Tltle 49,
which desmlbes thc lrbrllng rnC
ldentilicatlon requlrd. A DOT 4il X
4i erern nonflammlblc gee lsbgl gr
lag ie requhod lor common ggrrlcr
ahipments. Flgurt 2lllurtratce tht lr.
bel (black prlnting on graen) lhrt ia
rcqulred lo entpmcnt ol hcllum by
common oqrrlef,
Shlpmcntr by sh muct conform wlth
?jtlc 49 Codi ot Fsdorrl Fegulatlone
(FAA Fogulrttons). 49 CFR h ths gfit.
cirl publlcation of ths Dcprrtmant of
Trangportatlon Concornlne trihsport
ol hurrdour mrterlal by any rnodc.
Thuc regulatlonr are also lound in
lhr ClvllAergnaetlcs BoNro No, 82
Rrctrlated Articlas Tarlfi No, SD, but
tht deglgnation ot thls tArift rhry
chmgo lrom time to tlmg. Thc
wrlght llmllslloflr lor 3hrpglg 61
pl383n98r 0r gergo 8l?cfelt rcmiln
lho o|me.
Srlety Conrldrrrtlonr
Tho prlmary hrzetd lgtgcirltd wlth
giseoue hclium lB ths high praasure
involvod h 8torlge qnd clrvicl
equlpmenl. Aephyxlatton mry be a
haaard ln conffned aGrc.
FtouRg I
ValYer
The Compresced Gec Aagoclrtlon
and lh9 Amerlcan ltlationrlStrn.
drrds lnetltute hlvo rdopled a
throad nlze of 0,065 inch.l4 lnternal
rlght hancl thrgadr pcr hch d9elg.
netBd eB valw conncction l,lo, 680
(Flgure 1).
Salety Devlere
salety devices provlde protgcllon
agalnot oxc0s8iYc pressuro ln tho
Qpnldnfi. $ftcty devlcec aro parl ot
tho cylindrr valvoo or cttachmants to
ths lub0o. ThcEe devlces take tho
form ol frangibli dlece or erlgly OliCl
vslvos.
ldrntlllcrlion
Each cynndsr or tubg ft ldmtilicd
bit!,/oan the neckrlng and rhouldcr
byr
(t) DOT-3A or DOT.SAA-lhs
opecllicalione conlrolllng the
mrnutgEtvro ot thc contalngr,
lollo"ved by the eervicc prst.
sure rslln0 ln p9undO per
$mrr lnch,
tP) $ellel numbsr Of tho conlatner,
(3) Manullcturer's symbOlCnd thg
owner'e eymbol.
(1) Mgnth and year of thr oon-
telnet mgnufacture.
Bulldlngo
(l) Provlds rC0qudo wnilhllgn,
(e) Teet the etmosphaot in con.
flnsd work reae for oxygan
cgnt€nt, A 19.8% oxygan con.
osntr8tlon in lho 0lr ls tht mlnh
mum rccommondgd tor
vrotklng wilhout spoclrl brceth.
lng equlpmcnt.
FIGUBE 2
il0ll r[Ail[{ABtt 8AS
?
FRO14 5}IITH & CO}IPRNV
Gaseoue Helium
s3.22.1995 14! t4 P. 4
Genersl
Oareous hclium ls lnert, selsrless,
odorless, tt8lglgss, ngn-corroEivc,
and nonflammeble, lt lE the llght$t
rare ga6,
Helium lB a rnonelomlc, chgmlcally
hactlw gas. n wiff not rescr wtth
other elemonls 0r compoundg, undtr
ordinary condltlont,
$lnca hclium ls lngrt, spgclalcon.
rlruclion mttBrlsls gre nol ruquked.
V.crrlt rnd plplng ursd in hellurn
t.rvicc should bo doalgncd lo ttre
Amtlcen $oclg1y ol McchanlcrtEn-
ginacrs (ASME) or Doparlmcnt of
Trrntportrtlon (DOT) c0dc0 for the
Frcgsurgg and lgmpcratures
lnvolwd.
Hrlium la ueuelly oompeeeed lnto
ger cylindcre by olllubrlcatcd com.
pr9$90rF, Dry or wator lubrlcatd
comprcssion oyBtsms are eomctimce
used. Thc amount ol hellum con.
talncd in e cyllnder lc detarmlncd by
ths prt0cun ind tompgratun lor the
partlcular circd cyllnder usgd, ThG
hlgha thr pressure tho moro mlium
q9nlaincd in tho cyllndor.
The mglsgular oymbollor hellurn lo
lle.
Toxioily
Hellum lc odorlcce and nonloxlc, but
mrny producc rullocrtlon by {llutlng
tho conccnlretlon ol oxyitcn ln ilr
behw lcvels nacgsEtry to aupport
lifo. PEFSONNEL, INCLUDING RE8.cut woRKERt, SHoULO NOT EN.
TER AREAS WHEHE THE OXYOEN
coNcENTFATtof.l tS BELow 19.$s,
UNLESS PROV]DEO WTH A SELF.
CONTAINED BREATHING APPARA.
TUS OR AIB,LINE HESPIRATOR. Ex,
t oturr l0 oxygon.dstlcitnt
stmotphfrts mry produor dlzzl-
n088, nluiar, vomltlng, lo|t ol con.
oclousnc$. and doath. Dulh mry
r88ull lforfi CnOrS ln Jvctgtmcnt, con.
fu8lon, or logo ol wnrciournrer
whlch prcvtnto soll.te3cul, At low
oxygon concentretlont unconoclout.
no8s cnd dcith mty occur in mo.
ondc without wamlng.
Mlnulloturr
Hcllum le obtelnrd lrom natural gas
by r llquelrclion lnd ctrlpptng piee.
lgr, Llmllod tmounlt rro oblqlnsd
rl0o by llguolylng ind dlrllllhg slr.
Urol
Hellum lr urcd ll m lnert ohleldlng
gro lor src welding by the woldlng-
lndustry. Eleotrontc_ tuSgg coxtsh hg.
lium or mlxtures olhrlium. noon. and
rrgon, Anothsr uso fgr hclium l0 is
an lncrt grc rtffocphers lor lhr pro
ducllon ot rilcllw metqle, ruch as
zlrconlum rnd tltrnlum. Wcathtr bsl,
loons and diriglbler alco mrtc uac ol
hrllum'e proprrtics-low density
rnd nontlammoblllty.
Contalnere
Gageour helium ls shtppod end
llored ln hollow stoof cylinders or
tubeg.
Thc cyllnder hrs i conc0ve bt30
lr'hlch illowo thc oyllndo lo rtand
uprlght,8nd l9 laptrcd ro a rmlll
oponing on lhe top. The tapored or
opcn rnd lB throadcd to rocalvo i
cyllndcr vrlvg 0r othcr Butt|btc ouiltlqonmcthn, Salety rcilel dsvlcas rre
part of the cyllndu vttvG or the out.
l9l c:onncctlon. A thratclcd neck?ing
ls msurcd to rho tlptrrd 3nd ot thl
cylhdar to dlow o protrcllya cyllnder
cep to bt inrtilled,
Thc tube lt l,rpcrd on both mdr,
Each cnd has thnrdrd openlngr to
whish connoctlonl, vilvee, or cafcly
rlwiccs rre attachrd.
Thr tmount ol hctium that cen bo
contrincd ln r tubr il dcpendenl on
tho wrtar volumc tnd mrvlcg prgs.
0urc ol lhe tubo.
Cyllt6rrc mry be uegd individucily
or ln groupr, When ln grgupt, lha
cyllnclors should bc plped togsthor,
for ttdlonary storrgc or to lorm po(,
AUt btnks. Tlubes lro gcnerrlly
tnounlrd on lruck.trrilff chitsls, r0lt.
rood cff bedo, or plrcrd rt rtatlon,
ary locttlons u,hen lrroc lmounlt of
hsllum arc noeclsd.
Cyllndcr rnd TUb.r
Cylinders and tubco ire manuftc.
rured accordtng to D6p8rtment of
Traneportttlon.SA or DOT.SAA cpoci.
ficrtlont (fomsdy tnlQrulito com-
meroe Gommlratbn tCC
epeclltcrtlons), Cyllrrttrrs Bnd tuboc
in hellum ccrvlce arc hydrostslcaily
tcited vpon manufacturc, and evory
ten ycars therrtfter at 5/3 tinrce lhg
'trvicc
Preg9vrc.
Hellum mry bo storrd tn A$ME
codsd and stampod. Netlonel Board
rcglstered high.prsssure ga6 BtorSgo
FROII 5II I TH & COIIPRNV 03.22.1995 1{: t5
mnd$&GASES GROUP
MATERIAL SAFETY
DATA SHEET
P. 5
PRODUCTMilIE:
GHEilllGALllAlrll:
Hrllum, coiltpn$ed
Hrllum FORIIIULA: HcBYlDMfltF: Hdium gas. Or$ous hollum, Bdlmn gnr
UnrUFACTt Rli: Ar prottrob and Ctsnhatr, Ino.
7201 Hffinon Boulswrd
Allf,rtotflr, PA lgt0f . i50t
PR0DUCT${pitAlr0ll: I - 8m. ?92 - 1307
tlSDgmrftll[k 1008 EFFEWED fG: morlh tgo{iEVlH0t{: {
Hollum b rold rrpurp pmd,lt r m!6.
cA$il,fitBER t{{0-39-t
sr0stiEuttfB:
OEIA Notilfbft$od
ACOI+ $nplr uptryxhnt
ll0$* l{otu$llrtut
\
EtERpilrcYouEmfiHt
Hrllum ir r noolodo, odnL$-S{11nonllrmrnrbh g$ rromd lnoyltnrhn ct trtCh prurure. tt 0m cruso r4ld
*egru:Hidfr
'H.rcss'-ry;'ffi luF^mghl5ffi ffi 'ilffitrintl'
MNAEilqY NtPilOIG }T'TIER8
t00 . tA'ltt{ ln Conthcnld U.8.. Cenrtr rrnl puuto ilco
010. rltl '7711 oilrs loor[ont
Po[Erm Hfi lil EFFCT3
ItfilAA'lto{: gtrnDti $ilryile0l ]ldtum ie ngntoflo, Dut mcy €wt ilnoilllon by {lplcdru 0ro oa,non ln atr, lrct otdtnobnt olgem crn ooCIe nddnc lr{ury or OrrUr.
EllE C0|llAG{: No rdrnr.fhcr.
8l$l COIIIAGI: No ed'uto tftot.
GARClNooEitrC Fottt{llAk Hrllm lc rnl llrlrd rs c oomlmgrn a potentlll fldnogen W NTp, IARC, u oSHA S,npffi Z.tros,RE$wnilAlto[
RilrEtrEilIfrf: tnhrtrum
TAROFt0Rlllf* Nonc
EFFECI: Afhlxtdhn Fdtocruon)
t'lE0f EAt OOt0lTptl0 TCORAVATED Blf Otfi RGtpOurRE Nonc
rdl6rUon
polnbor
I
StTtlFItIT8: Epoem r mo,Vgrri drllobnt rhto?hcn (<tg.i$l.m', omr dzlncr. dorrlnqr. ilus., rronrturrg,sxoc$ nlivgthn, dtnlnithod nnntaldrrtns$. lo* otoohsdoi,i'riiifo-o6ut,-Effi;T'rdfilffii oontddrp &t0r orlrrr orygen rltl btng &ur unmnrcturno$ ivnrrour umnrno ild; ,ifikt', dr fJrifr,*frrl.iffi['r[O or Fotool&omrlvs.
irSDO' r00t?rt,) ato/ff i.v C,Da
tlrllutl rcr
FROI'I S}I I TH & CgilPFHV 85.22. 1995 l4: l6
,.'-.\
l
Ewqate rll ooronrrol llonr clt cl0d ana, lnooero vlnfirtion to rslsrse rm rnd mmlbroxygrn.levd, Ul r9prcPlrte
pmteortw eqghmht (SCBA). ll lnt lr fipra oonteln* or ifr ntrt, orll lho Atr Flodrrtr enrorgrtf hlophonr nunber. ll lerk ls h
iro/l rptem cior cyllnder velvt illd v.at prw$,o bdon dlfitPfim npdrt,
P. 6
UAEIIIS
?hb pmoflcc ot lnhntlonrlly lnhrllng hrllum ?or r uolce rllrdm rlhot h
crtrmolydongmur rd mry retull ln urlou: lnluryordlffit
ItfilAl.ATlOl* Percons luilcilng lrotrr laok ol orygen rmid bo moyod bfnrh dt ll Motlm ls not bnrlhing, afnlnlslsr ortltlclrl
rrflntlon. ll bnnthlng lr dllflcttll, rdn{nfbr owgorr. ODldn pottpt modfll rttrnllon.
EYE rSl$looilTAcf: Nqtedlo$r.
FtAtHPOtt{T At TolCXmoilTE}lP FtAttlil^ttluliltt
t{,A Nonllrmnrbb Nonflrmrnbb
EfiilOul$illt$ lllgDtft Hsllum lr nonllrmrr$ls ffd Scr nol $pport oorbu$on Uro rd4ulrhlrf mrdn *pnpdoto for hr
rwroundng fltr.
HAzAmOUl cotlBt silOll PRODlrdtS: Nonr
SPEC|AI RRE RomNg UFTRUCIIOIIE: Hrlium lr a dmilO $plrtrhnt, ll po$lblq ilrw| hdlun ayll;den ftofli m tnr or
oool wlth mtor. Sdf cmhlncd bnutltlto appltt[lt may be rrr$lnd lot rusow wo*en.
UiilTSUAL RRE AlO trlp8lotl IIIZARDS: tlpon upolurc h lnhn$ lf,lrt or nsme 0yll6fir slll nnl nddy
vtotently. Mot oyllnfrn rn rtolerpd to wnt o&hnb yfim opoeed to dryitad lurperrtunr. Proun ln a
rF dro'trc hrrt rrd lt rily ruptlll-ll polsurs dtsf dcvlor $oitld hll to tuttcton.
end or nptun
oonlalner crn bulld
JFij
SIORAGE: Cyllndm rhilld bt ilqlsd rrpdeht ln r udl-vrn$hlod. tsttf -$n,.plueotd tom r'l wrrthw. .$orege rm .
tcnrosrstum ihqrd not fioxd 125' F 62' Cl rnd rm rhqN be lm ol omburUble mffdl Sbttgo thould bt rwry lun
trerhhl tnvCsO unm mtl ernmmov uitr. AitlC amm nlrere rrlt or olhrr enodtrl mlhfilt til 9r080ttL Vchtl pobcdotl
c19c ind vofue outot rrlt *nriO ninrtn on Ct4lr$cr not mnnechd lor tra Sprnlr fuf frlin anply oy{ttdon Avold cxoolrlve
trnientory and storage lltrn, Urc r llal.ln fiatotn lnbm. l(ry good irwrntuy tmotdt.
ltAt&lUllo: 0o not rfrg, l!ll, or dldc oyl!n{s. Uts_r ltltrrblo hErdlnrct dGlenqd qor olltndr monment .
Nevs rtlotrpt t9 llft q
^
crltnrhr bv nr cq), g.cri! syltrder rt itl tim* wt{ts ln we. Ur r porurr-n*ring irgJrtot or $plnto conuol Yrh/r to rololy
dcchrfo-go ntin cyltndtr
-U$ . Ch.clt ylhn to ptsrent urfi!.llow hlo Ollilrr. Do not otrfpet qillff h lhOrlaeo
prp*uri oi CrctnrUi nb, ll unr crgelemo rU dlfiwlty open0ng cyllndr vdn, d$onlim urc and mntrct rt+pllq, .ltlovcr
l,tsort ln OJcot (r.d, {rtrnoh, loroidllvor, pry b$,lh,l lnto vdn crpdcnlngr. D@ !0 nW CIw80 yrlw c.tlliry I ll* tg
ooour. Ucc m ldurlrbla ttrtp.T/filh lo mmovr ovntght 0r lwhd cfl.
Hollum lr ggnpq1lUo wlh rll oornmm nnterlelr of comtnntlon, Pnnun lrqdnmaN{t ltlould bl 0ondffi mm llhgtlng
nrtodols ond Cdgnlne rylhm,
SPFCllt REQI IRSIEI{IB: Amn tloro rnd tundr srprTlod glrr ln roootd8noe sltt ConFnnad ooc A$oclrton, lno.
ffi lOa:lti.ggOO)prrphlrt CGA P.1, Sale Hamlltngothnpnwd Gtmrh Conlelnem. Loorl cgttlotlonr mry rquin
iprdtlo cqJlpmnt ltrt dolrgp ot ttro.
CAUTIQM Cornpnurd em cyllrrdec strsll not bt nfillod exopl by qudfibdPtoqoPq st mrptoqod gaseo' Shiprnt
d s eyltrdgwfrlotr trlr not biln fihd by hs mrrer or Hh 0rc ulme/r wfiltln oonrenl lr r vlolrllon d lcdeml lau
El*lll€ERltlo Coilfffill; Pmvldo gootl vrrdlallon andor loorl Ofrrud to pmvfit rqnnrlrdon d hlgh onorntrlfonc of ges.
0rrygen lrvrfu ln wulr rnr irould bommltond b ;tl;utl Utey do mt trt bclou l9.t!t,
REiFIRAIORf PROTECIIOTI
CENERAL UBE: NmrrrcdDd,
EMERO€NCV Usa SCBA or porl$ro pmlrn dt [na $th mosh end rccer pcok ln rner nfiil ol(ygfi o0noonlratm le <
19.$tt. Airpudrylng n$lnbil wlll mt proitde pd.c0on.
MIP'
PO. '
r l00cIto.oe R.Y ODl
Itdlum I 01.
FROH S}I I TH & COT4PANV 83.22.1995 143 t7_)
oTllERPROlEcnEB0lJlPilGl{?: Safety rtroco ra ncommended wtrn lnrrdilrg oyllldrn.
P. 7
:i
APFEARATICG: Colorlsr !n,
ilOl,ECULAR lrEnHT: i1.00
SpEdRC ORAury (Ar rt); At 70F Bt. tc) Js I Afn: 0,139
fTEEailc POlilrfiH.ilNg pONt: A tA!n: Nm.
0AS DENITYI At tOF Pt , 1 Cl rnd I Atm: 0.0103 tbs,tr3 (0. 165 ldms?
SoLUBIIIIYIHWATII: W.,\bt. d ]t F OCI 0.00e1
000ft Odofion.
B0lUlF FONI fl An0: 492,1'F (.260.9.c)
sEsFrc lolultE: 9t,71 ftl/rb (0.037 mtag)
V FORPRESIURFnTt0T): Nor rppflc$rr
CHEITICAL $IABLITY: thblr
OOt{UllOtlS ltt AIOO: Nonr
lll0OilPAilBlljlY: Nonr
,{AZARD0|| EcOtPrOSlTlOt PRODUCI8: Nonr
llA?ARDdrS P0LYilESlAilol* Uyili not occur.
Hoilum lt ! rlrplc r9hyrhnL.
Hrlium ls not todo. No rdrpreo oootqglrl rftob oo
chernlcals. llsllum lc not flotod ar I mrint pottutrnt
lrpochd, Hdlum &or not oontrln rny Ctru lor Chr ll orons dldrtltg
by00T t{s cFR t7r}.
\)
UMJSED PRODUST, EilPIY COIITAI}IER
mldurl or unund $rillltlo$.
Rotum onbhr end unurrdpmdw.t b npllrr, Do nol otmpt b dfolr of
DISFOML: Fot ltn$genoy dtpO$|, Oouo 0rr gllnd* ind Csrly dlfiil!| pr b tho rUnorytnre ln I wl$ vfitit ttd sroe ofout6oil.
DOTHAAfiDd48S; 2.2
DOTSlPPltlO UDEk llonfrmmrUr Gu
DOT dlFPnB MilE: Hrllum, Conpe*rd
pEilnncAno[mrllFm: uN rl,ffi
REFORilFLE QllAltltTlt IRQI l{onr
SPEqA[S0Pplll0lls0nil nOil gyttldrf rhould bo hrrryor0d ln r rcun uptght podton tn r *r[ wnUtrtrd tru,ck. l.toor
[BrEpori ln prnmgor oarpatll$l ol a rol{dr.
u,3. FSRII RFolfi,ATolts
EPA. EI{I'IROTT'IFIITAT PROIECIIOII ABEilCY
-_ .. CESll: Comlnhendve Eilmnm{rl Rfironr, Conprnruon, andtJrHlUAd ot fg00 nqrdne nosfioaUsoto thcNdifirl Rrqg!!-Clntr ot r nlorr ol qurnllUer of hprldour ans6nnr oqlrl'o or gr""b hdr u,i tporr*6 qrnuts
lRQl rn r0 cFR 302,r,
CERCLA ReMrbb Qrnntlt}l llon0.
,
tltbct r00cPrlb., tt$a0e Fw tl/ll N.llurr toll
FROI'1 Sr'r I TH & C0l'rPgNV
TBCA. TOXC STBSIAIICE COIIIFOL ACT : Hollun b ll$d on hr T00A lnwntory.
ostA. oGGtFAnow UFE1Y AllD HEAtlH lD]rrssTRAno]t
93.22.1995 14:t8
,\
l
P. I
SARA TTN.E [T $UPERFUND AI$TNDIilEI{T AND REAUTHORBTION ACT OF le$
tE0llOll Du: Roqufrlfiiruncy plrnnlng borod pn lh$hold phslne qmtltra Crpol rld ntomr qorting
boscd on rWorirble Wan[tler (RQ] ot EPA'o crfilmy hrnrrdotrr rubrhnobs (O eFR 3COl,
fiollum ls nol lirtrt rr rn Eftilrdy Hrqfrus $&rtonoo.
SE0llOtlttS: Rqrylor q$nl$lon 0l arurlnpotb ol nlum ql lodo ohcrolods thrt amow ln {0 CFR 372. Ihts
lnfomotlon .hqtld b. lndufu ln rll MBDSr that ao oopled rnd ddribuhd lor lhlr rnrlnlrt
l{ellum lr ndllshdll r toxlcdfinlorl.
l0 CFR PART 0C: Rill( Mrnrpmnt fot Chrmlcl Aoddert Rsbme hevmilon. Ro$/lm U10 dtrolo$mnt rnd
lrplomentrtor d tltt rilnfontnt pogrrru rt lrdll[r thrt rnrnuhdura, l[e, rton, a olhorivlor hrndr ngulrtlrt r$rhncrr
h qmiltlrr thrt excod TrilLd &ilollolth.
Hdlumlr ml ltrlnt $t nlulrtdr$clrnoO,
lECflONS 311 131* Rquln t$mlrrQn of mtcfil nt$ Oh shsts (MSD0r} rnd otrenrbal lrrvevrtory mporting wtur
i0ntlfigstlon of EPA donned huffi olrccrs. flr hsrd dtrr lor ilrlr prod$t srB:
IMMEDhTEHEALTH: Ns pRES$URE: y*
DEIJY€D}IFrtTH: No REA9TIMW: lh
f,AlltiAE[E: ib
2, CFi 10l0.llt: Ptmr Srtcty il{anrgocsrt of Hlghly Horrdou! ch.rirlstlr, Rrqdm lroflltlee to devolop r
prooorr $tity mrnremmt guenm bmod on Thrafffi Oumttco $a) d highfi bundotl chmloab.
aiil^
Hsllum h not Ufid lr r Hlffi Hradour Chmlod.
SrAlERE$JUnoXs
cAUFotrllA
Proposlllon 0$: Thlr pudncl dors NoT omhln lry llrhd $bslrnm vlrhh 0r $rb of Cdihmb D$lltt
wrdng mdnfitrhMr.
SCAQMDtule: \OG=IUA
]rAlAfrDiAllll08:ilfPAmflme: l0ll0iATtt{03:HEALTI{: 0 HEll.TH; 0
FUlriltABttTY; 0 RAililhSlljlt': 0
REACJllvlTv: 0 RFA0TMW: 0SPGCIAL: 6tr
'Corpn$rd Osr A$ooh0m natrlnonddlm lo drdgmh dmplr r*tUthnt.
"ND8'
IHPO,' t$ea tdaR0Alailrtlurt
***END*++
City and County of San Luis Obispo, Certified Unified Program Agency (CUPA)
Conditionally Exempt Small Quantity Generator
6'Silver-Only" Annual Self-Certification Program
I
\This form is for facilities that generate less than 27 gallons per month and accumulate no more
than275 gallons of "silver-only" hazardous waste at any time. If you qualify for using this form,
your facility will not require a physical inspection and you will be charged a small yearly fee.
Failure to complete and retum this form and the required receipts may result in an inspection and
an increased fee. If you treat your "silver only" waste on-site, this program does not apply to
your business. "silver only" hazardous wastes are wastes that are hazardous solely due to
the presence of silver.
Facility Name:
Facility Address
Type of Facility:
Date:
Contact Person:
Title/Position:
Phone Number:
Date/Dates of service
0o
Quantity of waste
removed/year:
Name of
Address:
n gal.I lbs
n
waste di contractor:
Phone Number:
Please attach copies of all your o'silver-only" waste disposal receipts from calendar
year 2007. Retain your original receipts for your own records.
Mail documents to:
City Fire Department
Attn: Molly Brown
2160 Santa Barbara Avenue
San Luis Obispo, CA9340I-5240
If you have questions please call Molly Brown at78l-7560
I certify under penalty of law that all hazardous waste containing for
recycling by the contractor listed above and that the above
Signature
tYr0nc\ 0f .{-
has
Name:
Position:
4
Date:2
accurate
?'
City and County of San Luis Obispo, Certified Unified Program Agency (CUPA)
Conditionally Exempt Small Quantity Generator
56Silver-Only" Annual Self-Certification Program
This form is for facilities that generate less than 27 gallons per month and accumulate no more
than 27 5 gallons of "silver-only" hazardous waste at any time. If you qualiff for using this form,
your facility will not require a physical inspection and you will be charged a small yearly fee.
Failure to complete and return this form and the required receipts may result in an inspection and
an increased fee. If you treat your "silver only" waste on-site, this program does not apply to
your business. ooSilver only" hazardous wastes are wastes that are hazardous solely due to
the presence ofsilver.
olt Date:o0
Contact Person:
l"itle/Position:
Phone Number:
^JFacility Name:
Facility Address:O
Type of Facility:
Quantity of waste
removed/year:
Name of waste disposal contractor:
Address:
Date/Dates of service:@r;6 treur.d*
r'g T*Sr^* olt* ,,w+
]" ot:,{ L'ts tY\€sS
*r1 'ff l^
)
Phone Number:
Please attach copies of all your "silver-only" waste disposal receipts from the year
2006, Retain your original receipts for your own records.
MaiI documents to:
City Fire Departmeni
Attn: Molly Brown
2160 Santa Barbara Avenue
San Luis Obispo, CA9340l-5240
If you have questions please call Molly Brown at78l-7560
I certify under penalty of law that all hazardous waste containing silver has been collected for
by the.contractor listedt_.;L (^L
4",,t^ I
above and that the above information is and accurate.
SignatureName:
Position:
U
i,i.i'ji'.\,'ajirt i)i,ri,': llil{..[: 1',t.:qi11:tr.-.t,i-:,JI..] i_-i t.i iji O 2tl0t_.
Date:tl ?4 2oo