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Home My WebLink About(2023) Survey - Transdev—Strata ENVIRONMENTAL September 13, 2023 City of San Luis Obispo Attention: Environmental Programs 879 Morro Street San Luis Obispo, California 93401 Class I Industrial Wastewater Discharge Permit Renewal (2023) First Transit, Inc. #55575 — San Luis Obispo, California Permit Number 419-I Strata Environmental Project Number 2258400A.55575.03.10 Dear Staff Member: Enclosed are the Class I Industrial Wastewater Discharge Permit Survey and the associated attachments for the First Transit, Inc. facility located at 29 Prado Road, San Luis Obispo, California. If you have any questions or require any additional information, please contact the undersigned at 865/539- 2077 or via email at mterrell@strataenv.com. Sincerely, STRATA ENVIRONMENTAL -MvAe--C��U Terrell Senior Environmental Scientist MMT:dlj Enclosures cc (w/ Enclosures): Jospeh Olaerts, Maintenance Manager, First Transit, Inc. 110 Perimeter Park, Suite E, Knoxville, TN 37922 a tel 866.539.2077 • fax 865.639.3970 • www.stralaenv.com 2258400A.55575.03.10.39656. docx ATTACHMENT A CLASS I INDUSTRIAL WASTEWATER DISCHARGE PERMIT SURVEY T. j - Public Utilities "I 879 Morro Street, San Luis Obispo, CA 93401-2710 BY• 805.781.7215 -----"------- Class 1 Industrial Wastewater Discharge Permit Survey Your business may discharge wastewater that falls under the City's Pretreatment Program §13.08. This survey will be used to identify whether a permit is needed. Make sure to fill out every field and sign the last page. if needed, Environmental Programs Staff will issue a permit within 30 days of receiving this completed survey. If you have any questions about this form or the permitting process, please call (805) 781-7426. SECTION 1- COMPANY INFORMATION A. Legal Business Name First Transit, Inc. B. Doing Business As (dba) First Transit, Inc. #55575 C. Facility Location Address: 29 Prado Road San Luis Obospo CA 93401 (street) (City) (State) (Zip Code) D. Mailing Address (SAME AS FACILITY LOCATION ❑YES) Attention: Joseph Olaerts Address110 Perimeter Park, Suite E Knoxville TN 37922 (street) (city) (state) (zip Cod E. Billing Address (SAME AS: FACILITY LOCATION ❑YES -OR- MAILING ADDRESS ®YES) Attention: - Address: _ (street) - (City) (state) (Zip Code) F. Authorized Representatives - Owner(s): a. Name: Joseph Olaerts Phone: 805-544-2730 b. Name: Terry Gillespie Phone: 805-544-2730 c. Name: Michael Olsen 512-845-0573 Phone: Title: Maintenance Manager Email: joseph.olaerts@transdev.com Email: Title: General Manager terry.gillespie@transdev.com Title: Dir. Env. & Sustainability Email michael.olsen@transdev.com Class I Industrial Wastewater Discharge Permit Survey G. Facility Contact Person Joseph Olaerts 805-544-2730 Phone: Email: H. Landlord/ Property Owner/ Management Company Titlejoseph.olaerts@transdev.com joseph.olaerts@transdev.com Property Manager/Owner Name: City of San Luis Obispo Address: 990 Palm Street San Luis Obispo CA 93401 (street} (City) (swe) (Zip Code) Phone: 805-781-7100 Email: www.slocity.org I. Number of employees: Full time 33 J. Hours of operation 4 : 30 0j/pm to 11 4 Part time am/pm K. Date operation began/or will begin? (mm/dd/yyyy) Days per week: S T W Th S (circle) am- pm Sat & Sun 07/01/2001 ***STOP*** DO THE OPERATIONS OR PROCESSES AT YOUR PLACE OF BUSINESS PRODUCE WASTEWATER, HAVE FLOOR DRAINS, OR WASH VEHICLES ONSITE? M YES --- CONTINUE TO SECTION No floor drains, washwater is reclaimed/recycled onsite ❑ YES, WASTEWATER IS PRODUCED, BUT HAULED OUT OF THE CITY --- CONTINUE TO SECTION 2. A PERMIT MAY BE REQUIRED. ❑ NO, WASTEWATER IS NOT PRODUCED NOR DISCHARGED TO THE SEWER AND THERE ARE NO FLOOR DRAINS. --= ENSURE SECTION ONE IS COMPLETE, SIGN THE LAST PAGE, AND RETURN THIS SURVEY. r 2 Class I Industrial Wastewater Discharge Permit Survey SECTION 2 - FACILITY A. Attach site plan of facility showing details of process areas, process plumbing, sewer lines, connections, appurtenances, water treatment or waste treatment processes, floor drains, chemical and waste storage areas. B. Indicate source of water supply and amount consumed per year. ( Note: 1 unit of water on bill = 750 gallons) Estimated Measured City of San Luis Obispo 650 gallons/month Well 0 _gallons/month ❑ ❑ Private Water System 0 gallons/month ❑ (_1 C. Does the facility discharge STORM WATER to the City of San Luis Obispo SEWER system? ® NO ❑ YES D. Average Operational /Production Days Per Year. 10 0 Average discharge Days Per Year. 10 0 SECTION 3 - OPERATIONS A. Standard Industrial Classification Code(s) (SIC) for your facility: 4111 B. North American Industry Classification System (NAICS) code: 485113 C. Provide a brief detailed description of the type of manufacturing, business processes, production, or service activities your firm conducts at this site: Transit bus maintenance and washing. Transit operators training and reporting location. D. List primary products produced at this site: N/A 3 Class I Industrial Wastewater Discharge Permit Survey E. Raw materials, chemicals, process additives used RAW MATERIAL, CHEMICAL, ADDITIVE (include SDS for each one listed below) QUANITY (PER MONTH) Antifreeze 25 gallons Motor Oil 60 gallons Transmission Fluid 12 gallons Gear Oil 10 gallons Windshield Washer Fluid 10 gallons Bus Wash 5 gallons (attach additional sheets if necessary) SECTION 4 — WASTEWATER INFORMATION A. If your facility employs processes in any of the industrial categories or business activities listed below, place a check beside the category or activity. ❑ Adhesives ❑ Aluminum Forming ❑ Anodizing ® Automobile Maintenance and Repair ❑ Battery Manufacturing OR Reclaiming ❑ Brewery ❑ Copper Forming ❑ Dairy Products Processing ❑ Electric/Electronic Components ❑ Electroplating ❑ Fruit or Vegetable Processing ❑ Hospital ❑ Inorganic Chemicals ❑ Iron & Steel ❑ Laundries ❑ Leather Tanning & Finishing ❑ Mechanical Products 4 ❑ Metal Etching/Chemical Milling ❑ Metal Coating (Phosphating, Coloring,) ❑ Nonferrous Materials ❑ Organic Chemicals ❑ Paint & Ink ❑ Petroleum Refining ❑ Pharmaceuticals ❑ Photographic Supplies ❑ Plastic & Synthetic Materials ❑ Plastics Processing ❑ Porcelain Enamel ❑ Printed Circuit Board Manufacturing ❑ Printing & Publishing ❑ Pulp & Paper ❑ Rubber ® Soaps & Detergent ❑ winery Class I Industrial Wastewater Discharge Permit Survey B. Types of wastes generated per operational day in Gallons Per Day (GPD). This section is aimed at how much overall waste is PRODUCED, not necessarily discharged into the sewer. Indicate Estimated (E) or Measured (M): 1. Process waste 2. Bolleritower blowdown 3. Cooling water, non -contact 4. Cooling water, contact 5. Food Processing waste (Cleaning food) S. Equipment/facility washdown 7. Air pollution control unit 8. Storm water runoff to sewer 9. Water Treatment 10.Other Bus Wash Average Flow (GPD) Maximum Flow (GPD) E1M Type of Discharge (Batch, Continuous, None) per Per Month N/A N/A N/A N/A N/A N/A N/A _ N / A N/A 50 gpd 100 gpd E Batch 8 TOTAL WASTES GENERATED 50 gpd J100 gpd E Batch 8 C. Water conditioning unit(s) (softener or demineralizer) used on site? ® No ❑ Yes: # of units: Salt ❑ Potassium ❑ Amount used for regeneration: Ibs/month D. Pretreatment devices or processes used for treating wastewater or sludge (check as many as appropriate): ❑ Air flotation ❑ Biological treatment, type ❑ Centrifuge ❑ Chemical precipitation ❑ Chlorination IN Clarifier, size 900 gallons ❑ Cyclone ❑ Filtration ❑ Flow equalization, capacity ❑ Grease or oil separation, size — gallons ❑ Grease interceptor, size - - gallons ❑ Grit removal ❑ Ion exchange 5 ❑ Neutralization, pH correction ❑ Ozonation ❑ Rainwater diversion or storage ❑ Reverse osmosis ❑ Screen ❑ Septic tank, size _ gallons ❑ Solvent separation ❑ Spill protection ❑ Sump, size gallons ❑ Other chemical treatment, type - ❑ Other physical treatment, type - - ❑ Other, type - — ❑ NO PRETREATMENT PROVIDED Class I Industrial Wastewater Discharge Permit Survey SECTION 5 — SPILL PREVENTION A. Do you have chemical storage containers, bins, or ponds at your facility? ® Yes ❑ No B. If you have chemical storage containers, bins, or ponds in manufacturing area, could an accidental spill lead to a discharge to: (check all that apply): ❑ An onsite disposal system ❑ Public sanitary sewer system (e.g. through a floor drain) ❑ Storm drain ❑ To ground ❑ Other, specify: ® Not applicable, no possible discharge to any of the above routes C. Do you have floor drains in your manufacturing or chemical storage area(s)? ❑ Yes ® No If yes, where do they discharge to? _ D. Do you have an accidental spill prevention plan (ASPP) to prevent spills of chemicals or slug discharges from entering the Control Authority's collection systems? ❑ Yes (Please enclose a copy with the application) ❑ No ® N/A, Not applicable since there are no floor drains and/or the facility discharge(s) only domestic wastes. REQUIRED ATTACHMENTS: ® SITE PLAN of facility showing details of process areas, process plumbing, sewer lines, floor drains, connections, appurtenances, water treatment, wastewater treatment processes, chemical storage area, waste storage area, and grease interceptor(s). . ® SDS for raw materials, chemicals, additives listed in Section 3, and additional sheets If needed. ❑ Accidental Spill Prevention Plan (ASPP) if you have one or have been required to write one. DO NOT SUBMIT APPLICATION WITHOUT THESE ATTACHMENTS 31 Class I Industrial Wastewater Discharge Permit Survey ***STOP*** ALL FIELDS ABOVE ARE REQUIRED TO BE COMPLETELY FILLED IN. FAILURE TO DO SO WILL RESULT IN A SURVEY BEING RETURNED AND A PERMIT BEING WITHHELD UNTIL A COMPLETE SURVEY IS SUBMITTED. AUTHORIZED REPRESENTATIVE STATEMENT 1 certify under penalty of law that this document and all attachments were prepared under my direction orsupervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based upon my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and/or imprisonment for knowing violations. Terry Gillespie NAME - AUTHORIZED REPRESENTATIVE SIG General Manager OFFICIAL TITLE 0q � oz DATE Submit completed surveys via mail or hand delivery to the following address: City of San Luis Obispo Attn: Environmental Programs 879 Morro Street San Luis Obispo, CA 93401 If you have any questions about this survey, please contact an Environmental Compliance Inspector: Keith Schwanemann 805-781-7426 kschwane@slocky.org Dylan Foster 805-781-7413 dfoster@slociity.org FOR OFFICE USE ONLY Reviewed by: Date: ❑ Issue Permit ❑ Incomplete, missing information ❑ Permit not required 7 ATTACHMENT B SITE MAP i I I a° J } Lu SAN LUIS OBISPO DEPARTMENT OF PUBLIC WORKS Q� cL LL L) 0 ,1O p 0 j APO w o �Z z w z m SHEET FLOW C7 z O¢ y g w x —x —x —x —x —x —x —x — J m ZW m J U� w W QL.. P J �a JV ? J LL J wu)J w Q' Q / p wa mo a w 3 of itLANDSCAPING ° z OZ Z w w w W W I -- ° O ° ° z O Ox 00 `_ i� m vi O> O U)i U) U co (n I O u z 0 I �} m zz O Q 1 •. x O _ 2 m J J �U zl I mw Q x EL W¢ v� " H� Lu w� N I 4w w > Fi w p " z Q Q I OFFICES Lu z O x o UU x O Q I I ++ In N U)i ¢ I 0 Z w a 1 Q yq�j 1 N Z a Q Q� z 0x O I Q x J •emu) C 7 W O 01 LL Q d I C N p O 0 Q ° W y' U In z w ¢ O w c�cI z " z fn H— x z O z j i z SHED z 1 5 o w co 10 O N I c m z Q oom_ iiW J Z _ O U F U x w U z ¢ ¢ f_UI ¢ ` w Q I > n- i � 00 d 00000 ' / 1 x " w ` " Q LLI OfO I O I W Q W x W N w 0 Q� N F p N a cr w n PARKING 1" 3 W, ai w z I >LL �E / 1 O o . W Wa / I wow a O a o~ I> t°z i 9 N 1 I NHO o w w z N a ° Q ZzQ // In o 1 ` w z m o o i> 00W / O W O w 1 O 1 1 ¢tea 3 O w U z Q ¢/ / = w I I x ofww(n- z L N h m ¢°w > m N z U W Z Z I z 1 I ° Y QQw W Q Z K Q F � U cn d F Q m a ( /. Op I x OF- W w o z 0 g o_Q woa�� a O o 0 2 z Qd ~w U PARKING 1 I LL. ro Q� J om d Q OF W¢ = I LL�-JO 1 Y N N ° OO > 1 I = OJ 1 2 W C d 7 NN R In w�Z°moo �i 0 0-c w z �w N z� w J Z� I 'I zW > W> LLi Jm0 cm Z cI > LL ai a 0 o N �_ J f d ¢ a w LUx w co OOOOO I wI O LL ornZ 2Q K O F W �tqY LLLL a O r ' moo � V' a4 Q m 0 ZaW A m �x� x— x— x— '— x— ■— x— x— a' da o m �J F o � G 1 3 w a �~ Z z 'n'� n N ® °a W,- ne ne O �(P f� JN W ZQ4 WASTEWATER TREATMENT PLANT 0 g m m N L C w u- �J= d U Q gQaU _ z U ° NLL� Od' LLG o o LL O ? - o 0 z IIII' z eMova oroz c�sss�seuwamo�ao:in �.seunn�:au ave iM��-ul me9tom9i cee v��:z ATTACHMENT C SAFETY DATA SHEETS (SDSs) Page 1 of 5 MATERIAL SAFETY DATA SHEET ADVANCED + ANTIFREEZE -BLEND ADVANCED LIQUID RECYCLING, INC. Please note that the MSDS for concentrate is being provided for the antifreeze products blended down with water. The information for the blended product is the same. General Information Company Name: ADVANCED LIQUID RECYCLING, INC. Company Street: 14 WEST MAIN STREET Company City: MER DEN Company State: CT Company Country: US Company Zip Code: 06451 Company Emergency Phone #: (203) 238-6771 Company Phone #: (203) 238-6771 Date MSDS Prepared: 8/5/03 Safety Data Review Date: 2/11/05 Hazard Ratings: HEALTH 1 FIRE 1 REACTIVITY 0 Ingredients/Identity Information Ingredient Sequence Number: 1 Ingredient: WATER CAS Number: 7732-18-5 Percent: —50 OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED NIOSH TWA: NOT ESTABLISHED Ingredient Sequence Number: 2 Ingredient: ETHYLENE GLYCOL CAS Nwnber: 107-21-1 Percent: 47 OSHA PEL: NOT ESTABLISHED ACGIH TLV: 100 ppm NIOSH TWA: NOT ESTABLISHED Ingredient Sequence Number: 3 Ingredient: DIETHYLENE GLYCOL CAS Number: 111-46-6 Percent: <3 ADVANCED + ANTIFREEZE -BLEND Page 2 of 5 OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED NIOSH TWA: NOT ESTABLISHED Ingredient Sequence Number: 4 Ingredient: PROPRIETARY Percent: <3 OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED NIOSH TWA: NOT ESTABLISHED Physical/Chemical Characteristics Appearance and Odor: CLEAR, BLUE-GREEN OR RED, ODORLESS LIQUID Boiling Point: 388° F Freezing Point: -34' F Vapor Pressure: 0.06 nm-iHg @ 68' F Vapor Density (Air--1): 2.1 Specific Gravity: 1.110-1.125 @ 60° F Liquid Density: 9.25-9.381b./gal @ 60' F Evaporation Rate: NOT AVAILABLE Solubility in Water: SOLUBLE pH. 10.0 —11.0 Fire and Explosion Hazard Data Flash Point: 232' F Flash Point Method: CC Lower Explosive Limit: 3.2 Upper Explosive Limit: 15.3 Autoignition Temperature: 7480 F Extinguishing Media: USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE -EXPOSED CONTAINERS COOL AND REDUCE FUMES. Special Fire Fighting Procedures: WEAR PPE AND NIOSH-APPROVED SCBA WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE AND APPROPRIATE TURN- OUT GEAR. Unusual Fire And Explosion Hazards: ABOVE FLASH POINT, VAPOR -AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS. CONTAINERS MAY BE EXPLOSIVE IN A FIRE. ADVANCED + ANTIFREEZE -BLEND Page 3 of 5 Reactivity Data Stable: YES Conditions to Avoid: HEAT, FLAMES, IGNITION SOURCES, AND INCOMPATIBLES. Materials to Avoid: STRONG OXIDIZING AGENTS AND STRONG BASES. Hazardous Decomposition Products: CO, CO2, ACRID SMOKE AND FUMES. Will Hazardous Polymerization Occur'? NO Health Hazard Data Route Of' Entry - Inhalation: INHALATION OF VAPORS IS NOT AN ISSUE UNLESS PRODUCT IS HEATED/MISTING. EXPOSURE TO VAPORS OVER EXTENDED TIME CAN CAUSE THROAT IRRITATION AND HEADACHE. MAY CAUSE NAUSEA, VOMITING, DIZZINESS, AND DROWSINESS. PULMONARY EDEMA AND CENTRAL NERVOUS SYSTEM DEPRESSION MAY DEVELOP. HEATED PRODUCT CAN PRODUCE RAPID, INVOLUNTARY EYE MOVEMENT AND EYE DAMAGE. Route Of Entry - Eyes/Skin: SPLASH IN EYES MAY CAUSE IRRITATION, PAIN, AND EYE DAMAGE. MINOR SKIN IRRITATION MAY OCCUR. 1Zoutu Of' 1 ntry - Ingestion: INITIAL SYMPTOMS PARALLEL ALCOHOL INTOXICATION, PROGRESSING TO CENTRAL NERVOUS SYSTEM DEPRESSION, VOMITING, HEADACHE, RAPID RESPIRATORY AND HEART RATES, LOWER BLOOD PRESSURE, STUPOR, COLLAPSE, AND UNCONSCIOUSNESS WITH CONVULSIONS. DEATH FROM RESPIRATORY ARREST OR CARDIOVASCULAR COLLAPSE MAY FOLLOW. LETHAL DOSE IN HUMANS IS 3-4 OUNCES. Carcinogen? NO Signs and Symptoms of Overexposure: STOMACH OR INTESTINAL UPSET, IRRITATION OF NOSE, THROAT, OR AIRWAYS, DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, OR UNCONSCIOUSNESS. Emergency/first slid Procedures: Inhalation: IMMEDIATELY MOVE TO FRESH AIR. SEEK MEDICAL ATTENTION. IF PERSON IS NOT BREATHING, BEGIN ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. Skin: REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. LAUNDER CLOTHES BEFORE REUSE. ADVANCED + ANTIFREEZE -BLEND Page 4 of 5 Eves: MOVE INDIVIDUAL TO FRESH AIR. FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST. Ingestion: IMMEDIATELY SEEK MEDICAL ATTENTION OR CONTACT POISON CONTROL CENTER. Precautions for Safe Handling and Use Steps If Material is Released or Spilled: IF SPILL IS SMALL, ABSORB LIQUID WITH PROPER ABSORBENT. IF SPILL IS LARGE, ELIMINATE ALL IGNITION SOURCES. STOP SPILL AT THE SOURCE. PREVENT SPILL FROM ENTERING THE ENVIRONMENT OR SPREADING. VENTILATE THE AREA. PUMP OR VACUUM PRODUCT TO CLEAN CONTAINERS FOR RECOVERY. ABSORB UNRECOVERABLE PRODUCT. NOTIFY PROPER AUTHORITIES IF SPILL REACHES THE ENVIRONMENT. Waste Disposal Method: DISPOSE OF MATERIAL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. Precautions-HandlinJStoring: HARIMFUL OR FATAL IF SWALLOWED. STORE IN A COOL, DRY, VENTILATED AREA. KEEP SEPARATE FROM ACIDS AND OXIDIZERS. Re_u� latory Requirements: SPILLS TO THE ENVIRONMENT MUST BE REPORTED TO REGULATORY AGENCY. ETHYLENE GLYCOL HAS A REPORTABLE QUANTITY (RQ) OF 5,000 lb. UNDER SARA TITLE III. Control Measures Respiratory Protection: NIOSH/MSHA AIR SUPPLIED RESPIRATORS ARE RECOMMENDED UNDER CONDITIONS WHERE EXPOSURE LIMITS MAY BE EXCEEDED. ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. AIR PURIFYING RESPIRATORS MAY BE WORN UNDER NORMAL HANDLING CONDITIONS. Ventilation: MECHANICAL (GENERAL OR LOCAL EXHAUST) VENTILATION TO MAINTAIN LEVELS BELOW EXPOSURE LIMITS. Protective Gloves: CHEMICAL RESISTANT GLOVES. Eye Protection: SAFETY GOGGLES OR GLASSES. Other Protective Equipment: IMPERVIOUS CLOTHES, BOOTS, ETC. EMERGENCY EYEWASH AND SHOWER SHOULD BE NEARBY. ADVANCED + ANTIFREEZE -BLEND Page 5 of 5 Label Data Common Name: ADVANCED + ANTIFREEZE DOT Proper Sliipping Name: NONE REQUIRED. Special Hazard Precautions: HARMFUL OR FATAL IF SWALLOWED. Label Name: ADVANCED LIQUID RECYCLING, INC. Label Street: 14 WEST MAIN STREET Label City: MERIDEN Label State: CT Label Zip Code: 06451 Label Country: US Label Emergency Number: (203) 238-6771 Disclaimer The above information is, to the best of our knowledge, current, accurate, and complete based on information reasonably available to us as of the date of the preparation of this form. However, it is the user's responsibility to determine the safety, toxicity, and suitability for his or her own use of the product described herein. Since the actual use by others is beyond our control, no guarantees, expressed or implied, are made by us as to the effects of such use or on the safety or toxicity of this product. Nor do we assume any liability arising out of use by others of this product. Nor is the information herein to be construed as absolutely complete, since additional information may be necessary or desirable when exceptional conditions or circumstances exist or because of applicable laws or regulations. Material Safety Data Sheet DURON TM -E SYNTHETIC 1OW-40 PEMMMADA 1 . Product and company identification Product name DURON TM -E SYNTHETIC 1 OW-40 Code DESYN14, 420-064 Material uses DURON-E Synthetic 1 OW-40 is a superior quality heavy duty engine oil which may be used in a wide range of 4 stroke compression and spark ignition engines in both mobile and stationary equipment over an extended temperature range. It has been especially formulated for use in on -highway 2007 EPA compliant engines which incorporate emission system aftertreatment technology. Manufacturer PETRO-CANADA P.O. Box 2844 150 — 6th Avenue South-West Calgary, Alberta T2P 3E3 In case of emergency Petro -Canada: 403-296-3000 Canutec Transportation: 613-996-6666 Poison Control Centre: Consult local telephone directory for emergency number(s). F2. Hazards identification Physical state : Viscous liquid. Odour : Mild petroleum oil like. WHMIS (Canada) : Not controlled under WHMIS (Canada). OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product. Emergency overview Routes of entry Potential acute health effects Inhalation Ingestion Skin Eyes Potential chronic health effects Chronic effects No specific hazard. Dermal contact. Eye contact. Inhalation. Ingestion. No known significant effects or critical hazards. No known significant effects or critical hazards. Slightly irritating to the skin. Slightly irritating to the eyes. No known significant effects or critical hazards. Carcinogenicity Not listed as carcinogenic by OSHA, NTP or IARC. Mutagenicity No known significant effects or critical hazards. Teratogenicity No known significant effects or critical hazards. Developmental effects No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Medical conditions Repeated or prolonged contact with spray or mist may produce chronic eye irritation and aggravated by over- severe skin irritation. Repeated skin exposure can produce local skin destruction or exposure dermatitis. See toxicological information (section 11) DURON n, -E SYNTHETIC 1OW--40 Page Number: 2 3. Composition/information on ingredients Name CAS number % Mixture of severely hydrotreated and hydrocracked base oil (petroleum). Mixture There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. The base oil may be a mixture of the following CAS#s: 8042-47-5, 64742-46-7, 64742-47-8, 64742-53-6, 64742-54-7, 64742-55-8, 72623-84-8, 72623-85-9, 72623-86-0, 72623-87-1, 178603-64-0, 178603-65-1, 178603-66-2, 445411-73-4 4. First -aid measures Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Inhalation Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Ingestion Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. 5. Fire -fighting measures Flammability of the product May be combustible at high temperature. Extinguishing media Suitable Use an extinguishing agent suitable for the surrounding fire. Not suitable None known. Special exposure hazards Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Products of combustion Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), calcium oxides (CaOx), zinc oxides (ZnOx), smoke and irritating vapours as products of incomplete combustion. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode. Special remarks on fire Low fire hazard. This material must be heated before ignition will occur. hazards Special remarks on Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or explosion hazards sources of ignition. 6. Accidental release measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8). DURON rM -E SYNTHETIC 10W--40 Page Number: 3 6. Accidental release measures Environmental precautions Avoid dispersal of spilt material and runoff and contact with sou, waterways, Grains ana sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaninq up Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note: see section 1 for emergency contact information and section 13 for waste disposal. 7. Handling and storage Handling Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Storage Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well -ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. 8. Exposure controls/personal protection Ingredient Exposure limits Mixture of severely hydrotreated and ACGIH TLV (United States). Notes: (oil mist) hydrocracked base oil (petroleum). TWA: 5 mg/m3 8 hour(s). STEL: 10 mg/m3 15 minute(s). Consult local authorities for acceptable exposure limits. Recommended monitoring If this product contains ingredients with exposure limits, personal, workplace atmosphere procedures or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Engineering measures No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Personal protection Respiratory Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: organic vapour filter DURON nN -E SYNTHETIC 1OW--40 Page Number. 4 8. Exposure controls/personal protection Hands Chemical -resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: neoprene, nitrile, polyvinyl alcohol (PVA), Viton. Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Skin Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they controls comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. 9 . Physical and chemical properties Physical state Viscous liquid. Flash point Open cup: 2350C (455°F) [Cleveland.] Auto -ignition temperature Fire Point: 257°C (494.6°F) Flammable limits Not available. Colour Light amber. Odour Mild petroleum oil like. Odour threshold Not available. pH Not available. Boiling/condensation point Not available. Melting/freezing point Not available. Relative density 0.8556 kg/L @ 15°C (59°F) Vapour pressure Not available. Vapour density Not available. Volatility Not available. Evaporation rate Not available. Viscosity 99.2 cSt @ 400C (104°F), 15.10 cSt @ 100°C (212°F), VI=160 Pour point -48°C (-54°F) Solubility Insoluble in water. 10 . Stability and reactivity Chemical stability The product is stable. Hazardous polymerisation Under normal conditions of storage and use, hazardous polymerisation will not occur. Materials to avoid Reactive with oxidising agents, acids, halogens and halogenated compounds. Hazardous decomposition May release COx, 112S, aldehydes, alkyl mercaptans, sulfides, methacrylate monomers, products smoke and irritating vapours when heated to decomposition. 11 . Toxicological information Acute toxicit Product/ingredient name Result Species Dose Exposure Mixture of severely hydrotreated and LD50 Dermal Rabbit >2000 mg/kg - hydrocracked base oil (petroleum). LD50 Oral Rat >5000 mg/kg - LC50 Inhalation Rat >2500 mg/m' 4 hours Dusts and mists Conclusion/Summary Not available. DURON nw -E SYNTHETIC 1OW--40 11 . Toxicological information Chronic toxicity Conclusion/Summary Not available. Irritation/Corrosion Conclusion/Summary Not available. Sensitiser Conclusion/Summary Not available. Carcinogenicity Conclusion/Summary Not available. Mutagenicity Conclusion/Summary Not available. Teratogenicity Conclusion/Summary Not available. Reproductive toxicity Conclusion/Summary Not available. 12. Ecological information Environmental effects Aauatic ecotoxicitv Conclusion/Summary Biodegradability Conclusion/Summary Other adverse effects : No known significant effects or critical hazards. : Not available. Not available. No known significant effects or critical hazards. 13. Disposal considerations Page Number: 5 1 Waste disposal The generation of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non -recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by- products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Disposal should be in accordance with applicable regional, national and local laws and regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. �_14. Transport information Regulatory information UN number Proper shipping name Classes PG* Label Additional information TDG Classification Not regulated. - DOT Classification Not available. Not available. Not available. - - PG* : Packing group DURON ,n, -E SYNTHETIC 1OW--40 Page Number. 6 15. Regulatory information United States HCS Classification Not regulated. Canada WHMIS (Canada) Not controlled under WHMIS (Canada). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. EU reaulations Risk phrases This product is not classified according to EU legislation. International regulations Canada inventory All components are listed or exempted. United States inventory All components are listed or exempted. (TSCA 8b) Europe inventory At least one component is not listed in EINECS but all such components are listed in ELINCS. Please contact your supplier for information on the inventory status of this material. 116. Other information Hazardous Material Health1 Information System (U.S.A.) Flammability Physical 0 Personal protection B National Fire Protection Association (U.S.A.) Flammability Health 0 ' Instability Special References Available upon request. TWMC Marque de commerce de Petro -Canada - Trademark Date of printing 9/11/2009. Date of issue 4 September 2009 Date of previous issue No previous validation. Responsible name Product Safety - JDW ® Indicates information that has changed from previously issued version. For Copy of (M)SDS The Canadian Controlled Products Regulations (CPR) (Under the Hazardous Products Act, part of the WHMIS legislation) only apply to WHMIS Controlled (i.e., hazardous) products. Therefore, the CPR and the 3-year update rule specified therein do not apply to WHMIS Non -Controlled products. Although this is true, customarily Petro -Canada reviews and updates Non -Controlled product MSDS if a customer requests such an update. These Non -Controlled product updates are given a lower priority than Controlled products but are handled as soon as practicable. If you would like to verify if the MSDS you have is the most current, or you require any further information, please contact: Internet: lubricants.petro-canada.ca/msds Lubricants: Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564 Ontario & Central Canada, telephone: 1-800-268-5850; fax: 1-800-201-6285 Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 1-800-201-6285 For Product Safety Information: (905) 804-4752 DURON Tm -E SYNTHETIC 1OW--40 Page Number: 7 16. Other information Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above -named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Material Safety Data Sheet HYDREXTM AW 22, 32, 46, 68, 80, 100 PORoc MAN 1 . Product and company identification Common name HYDREXTM AW 22, 32, 46, 68, 80, 100 Code HDXAW22, 490-138; HDXAW32, 490-139; HDXAW46, 490-140; HDXAW68, 490- 141; HDXAW80, 490-142; HDXAW10, 490-137 Material uses These products are designed for use as heavy duty hydraulic power transmission fluids and for lubrication where good anti -wear and anti -oxidation properties are required. They would typically be used in high-pressure hydraulic systems, machine tools, presses, compressors, pumps, gear sets, and centralized bearing lubrication systems. Manufacturer PETRO-CANADA P.O. Box 2844 150 — 6th Avenue South-West Calgary, Alberta T2P 3E3 In case of emergency Petro -Canada: 403-296-3000 Canutec Transportation: 613-996-6666 Poison Control Centre: Consult local telephone directory for emergency number(s). 2 . Hazards identification Physical state Viscous liquid. Odor Mild petroleum oil like. OSHAIHCS status While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this MSDS contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product. Emergency overview No specific hazard. Routes of entry Dermal contact. Inhalation. Ingestion. Potential acute health effects Eyes Slightly irritating to the eyes. Skin Slightly irritating to the skin. Inhalation No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Medical conditions Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or aggravated by over- prolonged contact with spray or mist may produce chronic eye irritation and severe skin exposure irritation. See toxicological information (section 11) �3. Composition/information on ingredients Name CAS number % Mixture of severely hydrotreated and hydrocracked base oil (petroleum). Mixture The base oil may be a mixture of the following CAS#s: 8042-47-5, 64742-46-7, 64742-47-8, 64742-52-5, 64742-54-7, 72623-84-8, 72623-85-9, 72623-86-0, 72623-87-1, 178603-64-0, 178603-65-1, 178603-66-2, 445411-73-4 4. First aid measures Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs. Skin contact Wash skin thoroughly with soap and water or use recognized skin cleanser. Get medical attention if irritation occurs. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. HYDREXnw A 22, 32, 46, 68, 80, 100 Page Number: 2 4 . First aid measures Ingestion Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If potentially dangerous quantities of this material have been swallowed, call a physician immediately. Protection of first -alders No action shall be taken involving any personal risk or without suitable training. 5. Fire -fighting measures Flammability of the product May be combustible at high temperature. Products of combustion Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), phosphorus compounds (POx) , calcium oxides (CaOx) , zinc oxides (ZnOx) , aldehydes , ketones , hydrocarbons , smoke and irritating vapours as products of incomplete combustion. Extinguishing media Suitable Use an extinguishing agent suitable for the surrounding fire. Not suitable None known. Special exposure hazards In a fire or if heated, a pressure increase will occur and the container may burst. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode. Special remarks on fire Low fire hazard. This material must be heated before ignition will occur. hazards Special remarks on Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or explosion hazards sources of ignition. 6. Accidental release measures Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment (see section 8). Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods for cleaning up Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensed waste disposal contractor. Note: see section 1 for emergency contact information and section 13 for waste disposal. 17. Handling and storage Handling Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk. Evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. If ingested, seek medical advice immediately and show the container or the label. Wear suitable protective clothing. Keep away from incompatibles. Storage Keep container tightly closed. Store away from incompatible materials (see section 10). Keep container in a cool, well -ventilated area. HYDREKTm A 22, 32, 46, 68, 80, 100 Page Number. 3 8 . Exposure controls/personal protection Product name Exposure limits Mixture of severely hydrotreated and ACGIH TLV (United States). Notes: (oil mist) hydrocracked base oil (petroleum). TWA: 5 mg/m' 8 hour(s). STEL: 10 mg/m' 15 minute(s). Consult local authorities for acceptable exposure limits. Engineering measures No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Personal protection Eyes Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. Skin Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory Use a properly fitted, air -purifying or air -fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Recommended: organic vapor filter Hands Chemical -resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: neoprene, nitrile, polyvinyl alcohol (PVA), Viton. Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. 9. Physical and chemical properties Physical state Viscous liquid. Flash point Open cup: >207°C (>404.6°F) [Cleveland.] Auto -ignition temperature Not available. Flammable limits Color Odor pH Boiling/condensation point Pour point Melting/freezing point Relative density Vapor pressure Vapor density Volatility Not available. Pale, straw -yellow. Mild petroleum oil like. Not available. Not available. 22: -45°C (-49°F); 32: -39°C (-38°F); -24°C (A 1 OF); 100: -30oC (-22°F) Not available. 0.8587 to 0.8728 kg/L @ 15°C (59°F) Not available. Not available. Not available. 46: -33°C (-270F); 68: -33°C (-27°F); 80: Odor threshold Not available. Evaporation rate Not available. Viscosity 22: 21.59 cSt @ 40oC, 4.26 cSt @ 100°C, VI=101; 32: 34.5 cSt @ 40°C, 5.68 cSt @ 100°C, VI=103; 46: 46.6 cSt @ 40°C, 6.94 cSt @ 100°C, VI=105; 68: 65.7 cSt @ 40°C, 9.4 cSt @ 100°C, VI=115; 80: 80.0 cSt @ 40°C, 9.71 cSt @ 100°C, VI=99; 100: 100.0 cSt @ 40°C, 11.32 cSt @ 100°C, VI=99 Solubility Insoluble in water. HYDREXTm AW 22, 32, 46, 68, 80, 100 Page Number: 4 9 . Physical and chemical properties LogKow Not available. Softening Point Not available. Dropping Point Not available. Penetration Not available. Physical/chemical Not available. properties comments 10 . Stability and reactivity Stability and reactivity The product is stable. Conditions of instability Not available. Incompatibility with various Reactive with acids and oxidizing agents. substances Hazardous decomposition May release COx, H2S, methacrylate monomers, aldehydes, alkyl mercaptans, products hydrocarbons, sulfides, smoke and irritating vapours when heated to decomposition. Hazardous polymerization Under normal conditions of storage and use, hazardous polymerization will not occur. F1_1 . Toxicological information Toxicity data Product/ingredient name Test Result Route Species Mixture of severely hydrotreated LD50 >5000 mg/kg Oral Rat and hydrocracked base oil LD50 >2000 mg/kg Dermal Rabbit (petroleum). LC50 >2500 mg/m3 (4 Inhalation Rat Specific effects Carcinogenic effects Mutagenic effects Teratogenicity / Reproductive toxicity Sensitization Ingestion Inhalation Eyes Skin Synergistic products hours) Not listed as carcinogenic by OSHA, NTP or IARC. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Slightly irritating to the eyes. Slightly irritating to the skin. Not available. 12. Ecological information Ecotoxicity data Product/ingredient name Environmental precautions Bioconcentration factor BOD and COD Biodegradable/OECD Mobility Special remarks on the products of biodegradation Species Period No known significant effects or critical hazards. Not available. Not available. Not available. Not available. Not available. Result HYDREXTM AW 22, 32, 46, 68, 80, 100 Page Number. 5 13. Disposal considerations Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Waste disposal The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non -recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. F14 . Transport information Regulatory UN number Proper shipping Class PG* Label Additional information name information TDG Classification Not - - - regulated. DOT Classification Not available. Not available. Not - - available. PG' : Packing group 15. Regulatory information United States HCS Classification Not regulated. Canada WHMIS (Canada) Not controlled under WHMIS (Canada). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. EU regulations Risk phrases This product is not classified according to EU legislation. International regulations International lists CANADA INVENTORY (DSL) Listed CHINA INVENTORY (IECS) Listed EC INVENTORY (EINECS/FLINGS) Listed TSCA 8(b) inventory Listed 16. Other information Hazardous Material Health1 Information System (U.S.A.) Fire hazard Reactivity 0 Personal protection B HYDREXTu A 22, 32, 46, 68, 80, 100 Page Number. 6 16 . Other information National Fire Protection Association (U.S.A.) Flammability Health 0Instability Special References Available upon request. TWMC Marque de commerce de Petro -Canada - Trademark Date of printing 9/26/2008. Date of issue 9/26/2008. Date of previous issue 12/27/2006. Responsible name Product Safety - JDW Version 3 For Copy of (M)SDS Internet: lubricants.petro-canada.ca/msds Lubricants: Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564 Ontario & Central Canada, telephone: 1-800-268-5850 and (905) 822-4222; fax: 1-800- 201-6285 Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 1-800-201-6285 For Product Safety Information: (905) 804-4752 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above -named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. SAFETY DATA SHEET PETRO-CANADA ATF D3M 000003001076 Version 4.1 SECTION 1. IDENTIFICATION Product name Synonyms Product code Revision Date 2020/01/16 PETRO-CANADA ATF D3M RDL 3882 Print Date 2020/01/16 ATFD3MP5R, ATFD3MP20, ATFD3MICT, ATFD3MIBC, ATFD3MDRR, ATFD3MDRM, ATFD3MDCT, ATFD3MC12, ATFD3M,ATFD3MBLK Manufacturer or supplier's details Petro -Canada America Lubricants LLC 115N Oak Park Avenue #1 C Oak Park IL 60301-1366 United States Telephone : +1 888-284-4572 Emergency telephone number Emergency telephone number : CHEMTREC: 1-800-424-9300; Poison Control Centre: Consult local telephone directory for emergency number(s). Recommended use of the chemical and restrictions on use Recommended use Automatic transmission fluid for most North American automobiles and for off -highway torque converters requiring C-4 type transmission fluid. It is also suitable as a hydraulic fluid and as a top -up in power steering systems. Not to be used in conditions where aerosols could be generated. Prepared by Product Safety: +1 905-491-0565 SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour viscous liquid dark red l Mild petroleum oil like. GHS classification in accordance with 29 CFR 1910.1200 Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Potential Health Effects Primary Routes of Entry Eye contact Ingestion Inhalation Skin contact Aggravated Medical Condi- : None known. Internet: lubricants.petro-canada.com/sds Page: 1 / 10 TM Owned or used under license. SAFETY DATA SHEET PETRO-CANADA ATF D3M 000003001076 Version 4.1 Revision Date 2020/01/16 tion Other hazards None known. Print Date 1 /16 IARC No component of this product present at levels greater than or equal to 0.1 % is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1 % is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture . Mixture Components Chemical name CAS -No. Concentration M w/w) lubricating oils (petroleum), C15-30, 72623-86-0 30 - 50 h drotreated neutral oil -based 20 - 30 lubricating oils (petroleum), C20-50, 72623-87-1 h drotreated neutral oil -based _ 1 - 5 distillates (petroleum), hydrotreated 64742-55-8 light paraffinic Methacrylate copolymer 1 - 5 Ethanol, 2,2'-iminobis-, N-tallow alkyl 61791-44-4 0.1 - 0.25 derivs. 2-(2-heptadec-8-enyl-2-imidazolin-1- 95-38-5 0.0025 - 0.025 yl)ethanol SECTION 4. FIRST AID MEASURES If inhaled Move to fresh air. Artificial respiration and/or oxygen may be necessary. Seek medical advice. In case of skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Wash clothing before reuse. Seek medical advice. In case of eye contact Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Internet: lubricants.petro-canada.com/sds Page: 2 / 10 TM Owned or used under license. SAFETY DATA SHEET PETRO-CANADA ATF D3M �aouMaau 000003001076 Version 4.1 Revision Date 2020/01/16 Print Date 2020/01/16 If swallowed Rinse mouth with water. DO NOT induce vomiting unless directed to do so by a physi- cian or poison control center. Never give anything by mouth to an unconscious person. Seek medical advice. Most important symptoms First aider needs to protect himself. and effects, both acute and delayed SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Unsuitable extinguishing No information available. media Specific hazards during fire- Cool closed containers exposed to fire with water spray. fighting Hazardous combustion prod- Carbon oxides (CO, CO2), smoke and irritating vapours as ucts products of incomplete combustion. Further information Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- Use personal protective equipment. tive equipment and emer- Ensure adequate ventilation. gency procedures Evacuate personnel to safe areas. Material can create slippery conditions. Mark the contaminated area with signs and prevent access to unauthorized personnel. Only qualified personnel equipped with suitable protective equipment may intervene. Environmental precautions Do not allow uncontrolled discharge of product into the envi- ronment. Methods and materials for Prevent further leakage or spillage if safe to do so. containment and cleaning up Remove all sources of ignition. Soak up with inert absorbent material. Non -sparking tools should be used. Ensure adequate ventilation. Contact the proper local authorities. SECTION 7. HANDLING AND STORAGE Advice on protection against None known. fire and explosion Advice on safe handling For personal protection see section 8. Internet: lubricants. petro-canada.com/sds Page: 3 / 10 TM Owned or used under license. SAFETY DATA SHEET PETRO-CANADA ATF D3M 000003001076 Versinn 4.1 Revision Date 2020/01/16 Print Date 2020/01/16 Smoking, eating and drinking should be prohibited in the ap- plication area. Use only with adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Do not ingest. Keep away from heat and sources of ignition. Keep container closed when not in use. Conditions for safe storage Store in original container. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in a dry, cool and well -ventilated place. Keep in properly labelled containers. To maintain product quality, do not store in heat or direct sun- light. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS -No. Value type Control parame- Basis (Form of ters / Permissible exposure) concentration lubricating oils (petroleum), 72623-86-0 TWA (Mist) 5 mg/m3 OSHA Z-1 C15-30, hydrotreated neutral oil -based TWA (Inhal- 5 mg/m3 ACGIH able fraction TWA Mist 5 m /m3 OSHA PO TWA Mist 5 m /m3 NIOSH REL STEL Mist 10 mg/m3 NIOSH REL lubricating oils (petroleum), 72623-87-1 TWA (Mist) 5 mg/m3 OSHA Z-1 C20-50, hydrotreated neutral oil -based TWA (Inhal- 5 mg/m3 ACGIH able fraction) TWA (Mist) 5 m /m3 OSHA PO TWA (Mist) 5 m /m3 NIOSH REL STEL (Mist) 10 m /m3 NIOSH REL Engineering measures No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Respiratory protection Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Filter type organic vapour filter Internet_ lubricants.petro-canada.com/sds Page: 4 / 10 TM Owned or used under license. SAFETY DATA SHEET PETRO-CANADA ATF D3M Pam+ 000003001076 Version 4.1 Revision Date 2020/01/16 Print Date 2020/01/16 Hand protection Material neoprene, nitrile, polyvinyl alcohol (PVA), Viton(R). Remarks Chemical -resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is nec- essary. Eye protection Wear face -shield and protective suit for abnormal processing problems. Skin and body protection Choose body protection in relation to its type, to the concen- tration and amount of dangerous substances, and to the spe- cific work -place. Protective measures Wash contaminated clothing before re -use Hygiene measures Remove and wash contaminated clothing and gloves, includ- ing the inside, before re -use. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold pH Pour point Boiling point/boiling range Flash point Fire Point Evaporation rate Auto -ignition temperature Upper explosion limit / Upper flammability limit Lower explosion limit / Lower flammability limit viscous liquid dark red Mild petroleum oil like. No data available No data available -54 °C (-65 °F) No data available 195 °C (383 -F) Method: Cleveland open cup 213 °C (415 °F) No data available No data available No data available No data available Vapour pressure : No data available Internet: lubricants. petro-canada.com/sds Page: 5 / 10 Tm Owned or used under license. SAFETY DATA SHEET PETRO-CANADA ATF D3M F "'ZOca►wa► 000003001076 Version 4.1 Revision Date 2020/01/16 Print Date 2020/01/16 Relative vapour density No data available Relative density No data available Density 0.8502 kg/1 (15 °C / 59 °F) Solubility(ies) Water solubility insoluble Partition coefficient: n- No data available octanol/water Viscosity Viscosity, kinematic 34.11 cSt (40 °C / 104 °F) 7.37 cSt (100 °C / 212 °F) Explosive properties Do not pressurise, cut, weld, braze, solder, drill, grind or ex- pose containers to heat or sources of ignition. SECTION 10. STABILITY AND REACTIVITY Possibility of hazardous reac- Hazardous polymerisation does not occur. tions Stable under normal conditions. Conditions to avoid No data available Incompatible materials Reactive with oxidising agents and reducing agents. Hazardous decomposition May release COx, NOx, SOx, smoke and irritating vapours products when heated to decomposition. SECTION 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Information on likely routes of : Eye contact exposure Ingestion Inhalation Skin contact Acute toxicity Product: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Remarks: No data available Assessment: The substance or mixture has no acute inhala- tion toxicity Remarks: No data available Assessment: The substance or mixture has no acute dermal toxicity Remarks: No data available Internet: lu bricants. petro-ca nada. corn/sds TM Owned or used under license. Page: 6 / 10 SAFETY DATA SHEET PETRO-CANADA ATF D3M 000003001076 Version 4.1 Revision Date 2020/01/16 Components: lubricating oils (petroleum), C15-30, hydrotreated neutral oil -based: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg, Acute inhalation toxicity LC50 (Rat): > 5.2 mg/I Exposure time: 4 h Test atmosphere: dust/mist Acute dermal toxicity LD50 (Rabbit): > 2,000 mg/kg, lubricating oils (petroleum), C20-50, hydrotreated neutral oil -based: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg, Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Product: Remarks LC50 (Rat): > 5.2 mg/I Exposure time: 4 h Test atmosphere: dust/mist LD50 (Rabbit): > 2,000 mg/kg, No data available Serious eye damage/eye irritation Product: Remarks No data available Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity No data available Reproductive toxicity No data available STOT - single exposure No data available STOT - repeated exposure No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish Remarks: No data available Internet: lubricants.petro-canada.com/sds rM Owned or used under license. vrt�ocaNana Print Date 2020/01/16 Page: 7 / 10 SAFETY DATA SHEET PETRO-CANADA ATF D3M 000003001076 Version 4.1 Revision Date 2020/01/16 Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Remarks: No data available Remarks: No data available Toxicity to microorganisms : Remarks: No data available Persistence and degradability Product: Biodegradability Remarks: No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available Print Date 2020/01/16 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues The product should not be allowed to enter drains, water courses or the soil. Offer surplus and non -recyclable solutions to a licensed dis- posal company. Waste must be classified and labelled prior to recycling or disposal. Send to a licensed waste management company. Dispose of product residue in accordance with the instructions of the person responsible for waste disposal. SECTION 14. TRANSPORT INFORMATION International Regulations IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good National Regulations 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION California Prop. 65 This product contains chemical(s) known to the State of Cali- fornia to cause cancer and/or to cause birth defects or other Internet: lubricants. petro-canada.com/sds Page: 8 / 10 TM Owned or used under license. SAFETY DATA SHEET PETRO-CANADA ATF D3M 000003001076 Version 4.1 Revision Date 2020/01/16 Print Date 2020/01/16 reproductive harm. The chemicals include: benzene 71-43-2 The components of this product are reported in the following inventories: DSL : On the inventory, or in compliance with the inventory TSCA IECSC SECTION 16. OTHER INFORMATION Further information NFPA 704: Flammability L � 41 N O i7 Full text of other abbreviations All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption. On the inventory, or in compliance with the inventory HMIS® IV: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal haz- ards or risks, and 4 representing signifi- cant hazards or risks. The "" represents a chronic hazard, while the "/" represents the absence of a chronic hazard. ACGIH USA. ACGIH Threshold Limit Values (TLV) NIOSH REL USA. NIOSH Recommended Exposure Limits OSHA PO USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA 8-hour, time -weighted average NIOSH REL / TWA Time -weighted average concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / STEL STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA PO / TWA 8-hour time weighted average OSHA Z-1 / TWA 8-hour time weighted average AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensa- tion, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Internet: lubricants. petro-canada.com/sds Page: 9 / 10 Tm Owned or used under license. SAFETY DATA SHEET PETRO-CANADA ATF D3M 000003001076 Version 4.1 Revision Date 2020/01/16 PM Print Date 2020/01/16 Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration asso- ciated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Har- monized System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dan- gerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - In- ternational Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Indus- trial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Admin- istration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop- ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu- lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc- es; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self -Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Sub- stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative For Copy of SDS Internet: lubricants.petro-canada.com/sds United States, telephone: 1-800-268-5850; fax: 1-800-201- 6285 For Product Safety Information: 1 905-491-0565 Prepared by : Product Safety: +1 905-491-0565 Revision Date : 2020/01/16 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US/EN Internet: lubricants. petro-canada.com/sds Page: 10 / 10 TM Owned or used under license. ITEM: 2U077 - CAR/TRUCK WASH 5 G MSDS: A5150 ORDER: 0185773390 DROP LOCATION: P1-209 MATERIAL SAFETY DATA SHEET (MSDS) This MSDS should be attached or kept with the respective product with which it is associated, NNIlgg090ItP&k#q6#AP!I.• ::.14!##ggq041It IIII 'vAh:\ P#IINA09IfIIN#11114N1 NAW49N4NNNNNNNNNNN#p NgNfl#NNNpNN NNgkHNNNNNNN4NNgNggo" 11#NghHg}INNNHBffq dgo" dNkA11mNilgtt fNNgtiN HATEkTA1. SAPE"1R :::l l.;:i 65156 ! (X. " IAHLF i1N��rA1}= if 4,v4m1,r1(7VS IC) AVi).TD: 11A .• .HAZARDOUS I3(.%YMSTTZA1TUtf: i<%�`'T•(H*I ( ) PL.Y Cx.Y1T( (X) W.Cf,T, �;_6te: l%Ir•3TTT.:Nii 'Ir „Im,Ta: lJ;.tr: Ni,=.t;Jr•,;C rK r'- I{AZARD(Xls Da[Y" ? , -• . Fsy�b i'I�1:?_f, 'YNRCiCx1C'P: GXII"3L :;F CFJiTi?p`1 It_Ii!: V HFAI.11i HAZARD 1NE•'ORMATION &FIRST AID PRO(-MURFS--_---'- .�."' A. (HRIZ1IC ff1:AIMI IfA ARCi: MNL: H. ?N9Ml(�L O:X•iti3T1CXfS A(X7RAVT,'r, HF O�: r.'REX`'!icdf iR.L.=: n- x' • ' 1J '1 d... C/. _...]rTG mm ..h_,f. _ATORY .: :.,,._...- •' :...:..: :...:.:: _ _ r19'F; Pi TIT-1: )XI IT; TAR('.: YES URIM: (X} NK) PROP fi` - ,.'=1•jial<.i l .. - l ) Yf'S H14IS 8-e+L N: R:AIL`;s STRIS G SIT'F^,CI i OF FI+!FICi!;1•Kri G FIRST' AID 3 -'`' :RY HIGH OF LUZMY MIMIC GVE'Iil!LFO Ui2F FRC :F11:1 )RES .,HTGN =id �IE;LtA'; !' };YF`3 X. RI?1RT �`>, "i'.Ti;I PK}, IiLJ:i1J f'�, F'Lfi.':7? -T1Y�r•_"d I�{T,y Wl ill WATER. 1RFXCA1Z! ANY CC:SJP=' - •- -• I IIJLyR7�Il3•T15 - C?I-S Nf T1Fsi3F 'O.SlIA(111,L) A(.Y, fill(T'IM 1 fA)0TCL1,1) r`-.7i.'_,. ii'._.'!:;`). <R. .., 6051-310-7 Ni r ; �i ...... .:.. .... .:. ,...: _.. _,."30 01:?-4 r ..-..�i?I!�,, xYT,:_''h, ._.. ,: I;1'id iauG •'i::;-' NE M.'3 �v g11A11A•'.1' 9i) is il'4:1.fI'i'iik? I<E:!;,51!'};iJ'1z71'I !f:'d)F_: 'lliz: L'FIj1,' LVANIA, NI34 : E..1-4;Y, ANi? I1j, ----- 11 PHYSICAL DATA —•- AE?PF�=.kFddCcl F"hill, i.._ VC-1=:'-.. .... ... ;SE?'. F VAPOR 6F:E,. If•". Hi. I '1 �7 v. i:_:. ,.:. _. • - III FIR-0 & ERPIOSION HAZARD a4' 7 FLI,:X_ W 1'liT �P INMR FOR AT I E P{INi11E:. 1F IRR TAPT-CEd O'1r::S Gl"P MR,ul C?1T, IlJ!IA[:F�CI(Y`I X flALL m, TO EY"xmi A7F., :FRkI'f7cl :J f1?',;PJ: TV nNNI (tV PE!S1S1', GQ, PT:h;7u T?:i; ME A M, AT112 1'104. :QK!F:; 1'Ii;Ar X (iv o71' J7FT1I:iI'CfirlL IK2 IJk: Y1.F.tJF"I OF' YLNPER j0h) LIA11 .CT A P;TYSICIAr! i441:t F.t,1I3:Y:'1 iXUL'ROl, CYI17 T TV-f2D lR D'14f. N-17Y•:k (3I?1F: Alv'f'11IRf; HY Wvill'1.1D A14 LIN(THSC.I.0119 PGTt YRd, Ni Vi:R. INfx.a3 IMCPCI•K; IN mi £iK;N X. RE m%e ,:i, :-'&tYNF:''>, WASt! i1K.iR(:�R�If,l WI'I}[ ;-r1AP 1:RL<TTT;`I+_i) T•1JD F•L�{lis:. isE' :EKRIiH": i;.-:Ld 01(1)ILS GS1' i.E'T)T (_ilL VI PRECATITION VOR SAFE HANDISNG AND USE MATERIAL IS SPTI,I,EI)%RP.E,R:SF`): F701-1 Lill M'Y-T'RSAL OR PIC'Y. 1%2 4r1.11 RTNSG W711{ wxrER. W TE.' DISItc'3AI,: F _,11,1 W A[J., FEIIEWL, STF�T"r,', AND Tf)(:AI, WAS"'L; I:E I1 d�PICF3,'. 1TANDLIAK3 & MX)R.I`A;: Y"E;F.P 0(1P OF' RRACU OF CF{:iTl}iFS. (1111IRS: FOMOW WN. vll.: HYGi?iN i'RP"C`C.-f4'r a.i. VII SPECIAL PR(YPFX:'I'ION iNFORMATIGN R la%I:[iAiY)ry: y X) P1C>i-1E 1 EJ iS`I' r'l) M I ) C ANI `I%f: 1( i} 6*.F:iSTF,NII.U.is tx'RrF ix) C'WF:1ICTILY RF:S 'ra:�r>• r�YF; PLr•".7}3?r_'1'T C:1•r: rR�IE Ja iF1Tt PRO1,201,1VF, :1 A: i_ W IN , . _,R Fk_ . t -N 1.. K ...-.. VIII D.O.T. INR)RMATION POP 'R 941IPTIM > PiFJ r:( IV RFACTYVI7Y DATA HAYJ:R1) C[AS_.. '!li'S CIIJ"lhtttic WI9.11 IF.E S+l3., : IWIT: AIM 107AL RUDLATI(IC, (xt"1L47.N::'life, WE CR "I"K)gAi'• 1)F' 1111r: ,Y.Id{Q7:, 1,4. t+t$9.TAUM VICIII NF:9i•LYT 11i PWAXX.'IS :.1ARTLT1Y, ILF.+.�I7: a7l�FilY Ii1'::J7 1HF. '(WNJOW. N/A: 4XII, PJ:'•t•i.f f.:-�LBJFJi,is :•� '.;: LttitiI:ES N%��: (3?71' F3`I'AtiI,.T_ln9�I)1 X�a �;C)I Page 1 of 4 MATERIAL SAFETY DATA SHEET ALR WINDSHIELD WASH ADVANCED LIQUID RECYCLING, INC. General Information Company Name: ADVANCED LIQUID RECYCLING, INC. Company_5treet: 14 WEST MAIN STREET Company City: MERIDEN Company State: CT Company Country: US Company Zip Code: 06451 Company EmerEncy_Phone 4: (203) 238-6771 Company Phone #: (203) 238-6771 Date MSDS_Prepared: 3/2/06 Safety Data Review Date: 3/2/06 Hazard Ratings: HEALTH 1 FIRE 2 REACTIVITY 0 Ingredients/Identity Information Ingredient Sequence Number: I Ingredient: METHANOL (METHYL ALCO140L) CAS Number: 67-56-1 Percent: S 26 OSHA PEL: 200 ppm ACGIH STEL: 250 ppm NIOSH TWA: 200 ppm Ingredient Sequence Number: 2 Ingredient: WATER CAS Number: 7732-18-5 Percent: >_ 71 OSHA PEL: NOT ESTABL TSHF,D ACGIH TLV: NOT ESTABLISIILD NIOSH TWA: NOT ESTABLISHED ------------------------------------- Ingredient Sequence Number: 3 Ingredient: PROPYLENE GLYCOL. CAS Number: 57-55-6 Percent: S 3.0 OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED NIOSH TWA: NOT ESTABLLTSHED Rev. 3/2/06 b d 90H I Aa (i k w0dj b g5ed °1VLN3WN0H1AN3 V-LV)-LS 90/L /ZL :POATeOOH w ALR WINDSHIELD WASH Page 2 of 4 Physical/Chemical Characteristics Appearance and Odor: BLUE LIQUID WITH. CHARACTERISTIC ALCOHOL ODOR Boilinm Point: 178°-212' Vapor Pressure (nun Hg a 70' F): 40 Vapor Density (Air=1): 1.1 Speci fic_Gravi ty : 0.96 Evaporation Rate and Ref: (BU AC = 1 ): <1 Solubility in Water: COMPLETE Fire and Explosion Hazard Data Flash Point: 105°-1500F Flash Point Method: TCC Lower Explosive Limit: 5,5 Upper Explosive Limit: 36.5 Fire Point: NONE, MATERIAL DOES NOT BURN USING AST M METHOD D 4206. Extineuishine, Media: N/A Special Fire Fighting Proccdures: N/A *Note: MATERIAL EXHIBITS A FLASH POINT BUT DOES NOT SUSTAIN A FIRE. Reactivity Data Stable: YES Conditions to Avoid -(Stability):, HEAT, SPARKS, FLAME, ELECTRIC EQUIPMENT & OTHER IGNITION SOURCES. Materials to Avoid: OXIDIZING MATERIALS. Iazardous Decomposition Products: CO, CO2 & UNIDENTIFIED ORGANICS, Will Hazardous Polymerization Occur? NO Health Hazard Data Route of Entry - Inhalation: IRRITATING TO EYES & MUCOUS MEMBRANES. Route of Entry - Skin: MAY CAUSE IRRITATION & DERMATITIS. CAN BE ABSORBED. ACUTE OVEREXPOSURE CAN CAUSE SERIOUS NERVOUS SYSTEM AND TARGET ORGAN DAMAGE. Route of Entry - Ingestion: CAN BE FATAL OR CAUSE BLINDNESS. CAN CAUSE IRREVERSIBLE NERVOUS SYSTEM DAMAGE. Carcinogen? NO signs/Symptoms of Overexposure: IRRITATION, BLINDNESS, NARCOSIS, HEADACHE, NAUSEA, VOMITING, DEFA'I TING, DRYING. Rev. 3/2/06 9 d 988ZS l05£9 'ON/trb:5l '1S/9tr: 5l 9007, l OH (18J) w0di S a6sd !"1V-LN3WN0HIAN3 V-LVH1S — feb:SL 90/L /ZL :PanzaOaH ALR WINDSIHELD WASH Page 3 of 4 Emergency/First Aid Procedures: Eves: FLUSH WITH WATER FOR 15 MINUTES, Skin: WASH WITH SOAP & WATER. Inhalation: REMOVE TO FRESH AIR. GIVE CPRJOXYGE-N IF NEEDED. Ingestion: INDUCE VOMITING IF CONSCIOUS. AFTER VOMITING, GIVE 2 TEASPOONFULS BAKING SODA IN WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. Precautions for Safe Dandling and Use Steps if Material Released/Spill: REMOVE IGNITION SOURCES. WEAK APPROPRIATE RESPIRATOR & OTHER PROTECTIVE CLOTHING. ATTEMPT TO CONTAIN RELEASE. REMOVE WITH VACUUM TRUCKS/PUMP TO STORAGE/SALVAGE VESSELS, SOAK UP RESIDUE WITH NON-COMBUSTIBLE ABSORBENT & PLACE IN DRUMS FOR DISPOSAL. Waste. Disposal Mcthod: DISPOSE OF IN AN APPROPRIATE DISPOSAL FACILITY 1N ACCORDANCE WITH FEDERAL, STATE, AND LOCAL, REGULATIONS. Precautions-Handlingl tori ).- KEEP CONTAINER CLOSED, DON'T STORE NEAR HEAT, SPARKS, ELECTRIC EQUIPMENT, FLAME, OR OXIDIZING MATERIALS. DO NOT STORE ABOVE 120°F. Other Precautions: VAPORS ARE, HEAVIER THAN AIR AND WILL COLLF,CT IN LOW PLACES. GROUND ALL, CONTAINERS WHEN TRANSFERRING LIQUID. USE NON - SPARKING TOOLS. Control Measures and PPE Respiratory Protection:. WEAR A NIOSH APPROVED POSITIVE PRESSURE SCBA IF THERE IS A CHANCE OF OVEREXPOSURE; OTHERWISE, WEAR AN APPROVED RESPIRATOR. Ventilation: EXPLOSION -PROOF VENTfLATION TO MAINTAIN VAPOR CONCENTRATION BELOW RECOMMENDED LIMITS. Protective Gloves: CHEMICAL RESISTANT. Eye Protection: GOGGLES OR FACE SHIELD. Other Protective Equipment: IMPERVIOUS GLOVES, APRON, BOOTS Rev. 3 /2/06 9 d 988Z£',09£9'ON/bb:9l'1S/96,51 90OZ l 030(la3) 9 e6?2d-`1V1N3WN0U1AN3 V1VH1S <- W0�3 `ev:9L 90/L /ZL :p0nTa00H ALR WINDSHIELD WASII Label Data Page 4 of 4 Label Required: YES Common Name: ALR WINDSHIELD WASH DOT Prover Shipping Name: Alcohols, .n.o.s. (methanol 5 26%), Combustible Liquid, UN1987, PG III Special Hazard Precautions: INGESTION MAY CAUSE BLINDNESS, NERVOUS SYSTEM DAMAGE, AND/OR DEATH. IRRITATING TO EYES, SKIN, AND RESPIRATORY TRACT. Label Name: ADVANCED LIQUID RECYCLING, INC. Label Street: 14 WEST MAIN STREET Label City: MERIDEN Label State: CT Label Zit) Code: 06451 Label Country: US Label Emergency Number: (203) 238-6771 Disclaimer The above information is, to the best of our knowledge, current, accurate, and complete based on information reasonably available to us as of the date of the preparation of this form. However, it is the user's responsibility to determine the safety, toxicity, and suitability for his or her own use of the product described herein. Since the actual use by others is beyond our control, no guarantees, expressed or implied, are made by us as to the effects of such use or on the safety or toxicity of this product. Nor do we assume any liability arising out of use by others of this product. Nor is the information herein to be construed as absolutely complete, since additional information may be necessary or desirable when exceptional conditions or circumstances exist or because of applicable laws or regulations. Rev. 3/2/06 L d 988d£ 105£9 'ONAtib S9 'WS/ :91 90R 1 0100J) L a6sd •`1V-LNHWN0H1AN3 V-LVH1S <- WOad `Ztl=SL 90/L /ZL .POAT000d